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Elastocapillary filling of deformable nanochannels

机译:弹性毛细管填充可变形的纳米通道

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The capillary filling speed of wetting liquids of varying viscosity and surface tension in hydrophilic nanochannels with an elastic capping layer has been analyzed. The channels, with a height just below 80 nm, are suspended by a thin flexible membrane that easily deforms due to the negative pressure which develops behind the moving meniscus. In the elastocapillary filling of the channels, two opposite effects compete: the decreased cross channel sections increase the flow resistance, while the Laplace pressure that acts as the driving force becomes more negative due to the increased meniscus curvature. Although the meniscus position shows a square root of time behavior as described by the Washburn relation, the net result of the induced bending of the membranes is a definite increase of the filling speed. We propose a relatively straightforward model for this elastocapillary process and present experimental results of the filling speed of ethanol, water, cyclohexane, and acetone that are found to be in good agreement with the presented model, for membrane deflections of up to 80% of the original channel height.
机译:分析了具有弹性覆盖层的亲水性纳米通道中粘度和表面张力变化的润湿液的毛细管填充速度。高度刚好低于80 nm的通道被薄的柔性膜所悬挂,该柔性膜由于在移动的弯液面后面产生的负压而容易变形。在通道的毛细管毛细管填充中,有两种相反的作用:减小的横向通道截面会增加流动阻力,而由于弯液面曲率的增加,作为驱动力的拉普拉斯压力会变得越来越负。尽管弯液面位置显示出时间行为的平方根,如沃什伯恩(Washburn)关系所述,但引起的膜弯曲的最终结果是填充速度明显提高。我们为该弹性毛细管过程提出了一个相对简单的模型,并给出了乙醇,水,环己烷和丙酮的填充速度的实验结果,发现与所提出的模型非常吻合,膜的偏转率高达80%。原始通道高度。

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