Mg segregation in Mg-rich Mg-Ni switchable mirror studied by Rutherford backscattering, elastic recoil detection analysis, and nuclear reaction analysis

摘要

Pd/Mg_(3.3)Ni films were prepared by dc sputtering deposition on three different substrates of glass, diamondlike carbon/Si, and Si. Hydrogenation and dehydrogenation cycles were performed on these samples simultaneously. The optical switching property due to the hydrogenation and dehydrogenation was monitored by the transmission of laser light via the glass substrate. The switching ability was totally lost after 120 cycles. We made comparative study of the composition change between the new (as-deposited) and old (after 120 switching cycles) samples by Rutherford backscattering (RBS), elastic recoil detection analysis (ERDA), and nuclear reaction analysis (NRA). From the RBS results we found out the segregation of a Mg layer between the Pd cap layer and the rest of the Mg-Ni layer. At the Pd/Mg interface in the old sample, thin MgO layer formed probably during the dehydrogenation process with O_2. ERDA showed that there is much hydrogen in the old sample. NRA displayed the depth profiles of hydrogen distribution in the old sample. It is revealed that much hydrogen is accumulated at the interface between the Pd cap layer and the segregated Mg layer. It can be concluded that the formations of oxide and hydride of the segregated Mg layer are the main reasons for the degradation of the Mg_(3.3)Ni switchable mirror.