Electromagnetic properties of NiZn ferrite nanoparticles and their polymer composites

摘要

The magnetic properties of polycrystalline NiZn ferrite nanoparticles synthesized using a polyol-reduction and coprecipitation reaction methods have been investigated. The effects on magnetization of synthesis approach, chemical composition, processing conditions, and on the size of nanoparticles on magnetization have been investigated. The measured room-temperature magnetization for the as-prepared magnetic nanoparticles (MNP) synthesized via polyol-reduction and coprecipitation is 69 Am~2 kg~(-1) and 14 Am~2 kg~(-1), respectively. X-ray diffraction measurements confirm spinel structure of the particles with an estimated grain size of ～80 nm obtained from the polyol-reduction and 28 nm obtained from these coprecipitation techniques. Upon calcination under atmospheric conditions at different temperatures between 800℃ and 1000℃, the magnetization, M, of the coprecipitated MNP increases to 76 Am~2 kg~(-1) with an estimated grain size of 90 nm. The MNP-polymer nanocomposites made from the synthesized MNP in various loading fraction and high density polyethylene exhibit interesting electromagnetic properties. The measured permeability and permittivity of the magnetic nanoparticle-polymer nanocomposites increases with the loading fractions of the magnetic nanoparticles, suggesting control for impedance matching for antenna applications.