An experimental study of the soot formed in the pyrolysis of acetylene

摘要

A study of the formation of soot from the pyrolysis of acetylene has been performed in laboratory scale using a quartz reactor heated by an electric oven. The work includes a systematic parametric study in which we have varied: temperature (800, 900, 1000 and 1100℃), initial hydrocarbon concentration (1,5 and 10% of acetylene), space time (8.1 and 16.2 s), presence and oxygen concentration (0 and 1000 ppm), and presence and level of water (0,3 and 15%). In those experiments, we quantified the soot formed, which was further characterized through ultimate analysis, determination of BET area and SEM techniques, and we also determined the outlet concentrations of CO, CO_2 and different gaseous hydrocarbon species (C_2H_2, CH_4, C_2H_6, C_2H_4 and C_6H_6). The results show that increasing the reaction temperature and the initial concentration of C_2H_2, as well as the space time, results in favouring the formation of soot. The amount of soot formed exhibits a maximum in presence of oxygen and water in the reactant mixture.