Efficient, Aerobic, Ruthenium-Catalyzed Oxidation of Alcohols into Aldehydes and Ketones

摘要

In summary, we have discovered that TPAP can be used as an effective catalyst for the aerobic oxidation of alcohols to aldehydes and ketones. To the best of our knowledge, this novel procedure supersedes any previously reported aerobic, catalytic oxidations of alcohols by virtue of its simplicity, efficiency, and versatility. Although much work still remains, mild and ecologically benign aerobic oxidations of alcohols now appear to be within reach.