New Boranophosphorylation Reagents, Dimethyl Boranophosphate Monopotassium Salt and Tetramethyl Boranopyrophosphate

摘要

In conclusion, we have prepared new reagents, dimethyl boranophosphate monopotassium salt and tetramethyl bor- anopyrophosphate, and have demonstrated that these reagents react with reactive organic halides or lithium alkoxides in a nucleophilic or electrophilic manner. These facts open new and simple synthetic routes to various boranophosphates derivatives including borano analogues of naturally occurring phosphates.