Removal of Carbonyl Sulfide Using Activated Carbon Adsorption

摘要

Wastewater treatment plant odors are caused by compounds such as hydrogen sulfide (H_2S), methyl mercap-tans, and carbonyl sulfide (COS). One of the most efficient odor control processes is activated carbon adsorption; however, very few studies have been conducted on COS adsorption. COS is not only an odor causing compound but is also listed in the Clean Air Act as a hazardous air pollutant. Objectives of this study were to determine the following: (1) the adsorption capacity of 3 different carbons for COS removal; (2) the impact of relative humidity (RH) on COS adsorption; (3) the extent of competitive adsorption of COS in the presence of H_2S; and (4) whether ammonia injection would increase COS adsorption capacity. Vapor phase react (VPR; reactivated), BPL (bituminous coal-based), and Centaur (physically modified to enhance H_2S adsorption) carbons manufactured by Calgon Carbon Corp. were tested in three laboratory-scale columns, 6 in. in depth and 1 in. in diameter. Inlet COS concentrations varied from 35 to 49 ppm_v (86-120 mg/m~3). RHs of 17%, 30%, 50%, and 90% were tested. For competitive adsorption studies, H_2S was tested at 60 ppm_v, with COS at 30 ppm_v. COS, RH, H_2S, and ammonia concentrations were measured using an International Sensor Technology Model IQ-350 solid state sensor, Cole-Parmer humidity stick, InterScan Corp. 1000 series portable analyzer, and Drager Accuro ammonia sensor, respectively. It was found that the adsorption capacity of Centaur carbon for COS was higher than the other two carbons, regardless of RH. As humidity increased, the percentage of decrease in adsorption capacity of Centaur carbon, however, was greater than the other two carbons. The carbon adsorption capacity for COS decreased in proportion to the percentage of H_2S in the gas stream. More adsorption sites appear to be available to H_2S, a smaller molecule. Ammonia, which has been found to increase H_2S adsorption capacity, did not increase the capacity for COS.