Crystallization Behavior of Synthesized CaO-SiO_2-CaF_2-La_2O_3 Rare Earth-containing Slag

摘要

Crystallization behaviors of CaO-SiO_2-CaF_2-La_2O_3 synthesized slag with different basicity have been studied by differential scanning calorimetry (DSC), field emission scanning electron microscopy (SEM) and X-ray diffraction (XRD). It was found that there were mainly three kinds of crystalline phases (La_(7.58)(Sl_(1.048)O_4)_6O_2, CaSiO_3 and Ca_4Si_2O_7F_2) precipitated in the slag during the cooling process. Crystalline phase Ca_2SiO_3 formed when the basicity was increased to 1.3. The observations confirmed that the rare earth phase (La_(7.58)(Si_(1.048)O_4)_6O_2) precipitated firstly in each slag during the cooling process. With the increase of slag basicity, the crystallization temperature of the rare earth phase decreases while the precipitation peak temperature of CaSiO_3 and Ca_4Si_2O_7F_2 increase. The morphology of rare earth phase is hollow hexagonal which is filled with substrate phase. The optimum condition for crystallization and separation of rare earth phase was obtained. The basicity of the slag should be controlled between 0.9 and 1.1. The morphology of rare earth phases can grow much better after isothermal heat treatment for 4 h at the crystallization temperature of rare earth phases. The mean size of rare earth phase could increase to more than 60 μm by isothermal heat treatment.