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Conducting polymer-coated stainless steel bipolar plates for proton exchange membrane fuel cells (PEMFC)

机译:用于质子交换膜燃料电池(PEMFC)的导电聚合物涂层不锈钢双极板

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Stainless steel satisfies many of the requirements for proton exchange membrane (PEM) fuel cell bipolar plates except its corrosion under fuel cell operating conditions. Metal oxide formation leads to contact resistance, and metal dissolution can cause contamination of the membrane electrode assembly (MEA). These problems can be solved by coating stainless steel plates with corrosion resistant and conductive layers. In this study, 304 stainless steel was coated electrochemically with the conducting polymers polyaniline (PANI) and polypyrrole (PPY). Cyclic voltammetry was used for the polymerization and deposition of these polymers. The polymer-coated stainless steel plates were tested for corrosion and contact resistance under PEM fuel cell conditions, which showed improved corrosion resistance with acceptable contact resistance.
机译:不锈钢满足质子交换膜(PEM)燃料电池双极板的许多要求,除了在燃料电池工作条件下的腐蚀。金属氧化物的形成会导致接触电阻,金属溶解会导致膜电极组件(MEA)的污染。这些问题可以通过在不锈钢板上涂上耐腐蚀和导电的层来解决。在这项研究中,用导电聚合物聚苯胺(PANI)和聚吡咯(PPY)对304不锈钢进行电化学涂覆。循环伏安法用于这些聚合物的聚合和沉积。测试了涂有聚合物的不锈钢板在PEM燃料电池条件下的耐腐蚀性和接触电阻,显示出改善的耐腐蚀性和可接受的接触电阻。

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