Enabling inexpensive metallic alloys as SOFC interconnects: An investigation into hybrid coating technologies to deposit nanocomposite functional coatings on ferritic stainless steels

摘要

Reduced operating temperatures (600-800 ℃) of solid oxide fuel cells (SOFCs) may enable the use of inexpensive ferritic steels as interconnects. Due to the demanding SOFC interconnect operating environment, protective coatings are required to increase long-term stability. In this study, large area filtered arc deposition (LAFAD) and hybrid filtered arc-assisted electron beam physical vapor deposition (FA-EBPVD) technologies were used to deposit two-segment coatings with Cr-Al-Y-O nanocomposite bottom segments and Mn-Co-O spinel-based top segments. Coatings were deposited on ferritic steels and subsequently annealed in air for various times. Surface oxidation was investigated using SEM/EDS, XRD and RBS analyses. Cr-volatilization was evaluated by transpiration and ICP-MS analysis of the resultant condensate. Time-dependent area specific resistance (ASR) was studied using the four-point technique. The oxidation behavior, Cr volatilization rate, and ASR of coated and uncoated samples are reported. Significant long-term ( ＞ 1000h) surface stability, low ASR, and dramatically reduced Cr-volatility were observed with the coated specimens. Improvement mechanisms, including the coating diffusion barrier properties and electrical conductivity are discussed.