Perovskite Conversion Coatings as Novel and Simple Approach for Improving Functional Performance of Ferritic Stainless Steel SOFC Interconnects          href='#fuce201900073-note-0001'/>

摘要

Abstract > A novel type of iron conversion process has been recently developed to produce dense and adherent LaFeO <sub>3</sub> perovskite coatings onto ferritic stainless steel surfaces by reaction with La <sub>2</sub> O <sub>3</sub> dissolved in specially‐formulated alkali molten carbonate baths. The major application of LaFeO <sub>3</sub> perovskite coatings is for use as electrically conductive and Cr barrier layers for enhancing the functional performance of solid oxide fuel cell (SOFC) stainless steel interconnects. An overview of the molten salt bath conversion process including the effect of chemical accelerants on structure and morphology of the deposited perovskite coatings is illustrated in this work. Latest results on SOFC coating functional properties obtained in recent European Union (EU) funded projects are also briefly mentioned. In particular, the tight correlation between coating thickness and electrical functional properties in terms of area specific resistance is highlighted here. Although thickness dependency may indicate a mediocre electrical conductivity of LaFeO <sub>3</sub> coatings produced by the conversion process, nonetheless very promising ASR results could be obtained in SOFC cathode environments at 700?°C with optimized coating structures and appropriate low coating thickness, thus suggesting a high potential of the conversion process for SOFC interconnect applications. </abstract> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> <div class="translation abstracttxt"> <span class="zhankaihshouqi fivelineshidden" id="abstract"> <span>机译：</span><Abstract Type =“Main”XML：Lang =“en”> <标题类型=“main”>抽象</ title> > 最近开发了一种新型的铁转换过程，以产生密集和粘附的Lafeo <sub> 3 </ sub> 通过与La反应，钙钛矿涂层通过反应通过反应到铁素体不锈钢表面上 <sub> 2 </ sub> O. <sub> 3 </ sub> 溶解在专用配方的碱熔融碳酸盐浴中。 Lafeo的主要应用 <sub> 3 </ sub> Perovskite涂层用于导电和Cr阻挡层，用于提高固体氧化物燃料电池（SOFC）不锈钢互连的功能性能。在这项工作中示出了包括化学促进剂对沉积的钙钛矿涂层结构和形态的影响的熔盐浴转化过程的概述。还简要介绍了最近欧盟（欧盟）资助项目中获得的SOFC涂层功能性质的最新结果。特别地，在此突出显示涂层厚度和电功能性能之间的紧密相关性。尽管厚度依赖性可能表示Lafeo的平庸电导率 <sub> 3 </ sub> 通过转换过程产生的涂层，尽管如此，可以在700°C的SOFC阴极环境中获得非常有前途的ASR结果，其具有优化的涂层结构和适当的低涂层厚度，因此表明SOFC互连应用的转换过程的高潜力。 </ p> </摘要> </span> <span class="z_kbtn z_kbtnclass hoverxs" style="display: none;">展开▼</span> </div> </div> <div class="record"> <h2 class="all_title" id="enpatent33" >著录项</h2> <ul> <li> <span class="lefttit">来源</span> <div style="width: 86%;vertical-align: text-top;display: inline-block;"> <a href='/journal-foreign-24199/'>《Fuel cells》</a> <b style="margin: 0 2px;">|</b><span>2020年第3期</span><b style="margin: 0 2px;">|</b><span>共7页</span> </div> </li> <li> <div class="author"> <span class="lefttit">作者</span> <p id="fAuthorthree" class="threelineshidden zhankaihshouqi"> </p> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zkzz" style="display: none;">展开▼</span> </div> </li> <li> <div style="display: flex;"> <span class="lefttit">作者单位</span> <div style="position: relative;margin-left: 3px;max-width: 639px;"> <div class="threelineshidden zhankaihshouqi" id="fOrgthree"> </div> <span class="z_kbtnclass z_kbtnclassall hoverxs" id="zhdw" style="display: none;">展开▼</span> </div> </div> </li> <li > <span class="lefttit">收录信息</span> <span style="width: 86%;vertical-align: text-top;display: inline-block;"></span> </li> <li> <span class="lefttit">原文格式</span> <span>PDF</span> </li> <li> <span class="lefttit">正文语种</span> <span>eng</span> </li> <li> <span class="lefttit">中图分类</span> <span><a href="https://www.zhangqiaokeyan.com/clc/1817.html" title="电化学工业">电化学工业;</a></span> </li> <li class="antistop"> <span class="lefttit">关键词</span> <p style="width: 86%;vertical-align: text-top;"> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Conversion Coating&option=203" rel="nofollow">Conversion Coating;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Interconnect&option=203" rel="nofollow">Interconnect;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Molten Carbonates&option=203" rel="nofollow">Molten Carbonates;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Perovskite&option=203" rel="nofollow">Perovskite;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Solid Oxide Fuel Cell&option=203" rel="nofollow">Solid Oxide Fuel Cell;</a> <a style="color: #3E7FEB;" href="/search.html?doctypes=4_5_6_1-0_4-0_1_2_3_7_9&sertext=Stainless Steel&option=203" rel="nofollow">Stainless Steel;</a> </p> <div class="translation"> 机译：转化涂层;互连;熔融碳酸盐;钙钛矿;固体氧化物燃料电池;不锈钢; 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