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Hydrogen generation by water electrolysis using carbon nanotube anode

机译:使用碳纳米管阳极通过水电解制氢

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摘要

Anode made of multiwalled carbon nanotubes (MWNT) results in enhancement of exchange current density compared to graphite anode in a conventional alkaline water electrolysis cell. The hydrogen production rate with the nanotubes was measured to be ~3751h~(-1)m~(-2) at pH ~ 14 which was nearly double of that obtained from traditional graphitic carbon electrodes at the same overpotential. This effect appears to be caused by defects on the nanotubes which reduces the energy barrier for the dissociation of OH- into oxygen at the anode.
机译:与传统碱性水电解槽中的石墨阳极相比,由多壁碳纳米管(MWNT)制成的阳极可提高交换电流密度。在pH〜14时,测得的纳米管制氢速率为〜3751h〜(-1)m〜(-2),几乎是在相同的超电势下从传统石墨碳电极获得的氢气的两倍。这种作用似乎是由纳米管上的缺陷引起的,该缺陷降低了阳极处OH-分解为氧的能垒。

著录项

  • 来源
    《International journal of hydrogen energy》 |2010年第9期|3945-3950|共6页
  • 作者单位

    Department of Physics, Banaras Hindu University, Varanasi 221005, India;

    rnDepartment of Chemical Engineering, Institute of Technology, Banaras Hindu University, Varanasi 221005, India;

    rnDepartment of Physics, Southern Illinois University, Carbondale, IL 62901, USA;

    rnMechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, NY 12180, USA;

    rnDepartment of Mechanical Engineering & Materials Science, Rice University, Houston, TX 77005, USA;

    rnDepartment of Physics, Banaras Hindu University, Varanasi 221005, India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    carbon nanotubes; hydrogen production; water electrolysis;

    机译:碳纳米管;制氢水电解;
  • 入库时间 2022-08-18 00:29:24

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