Ferrite/zirconia-coated foam device prepared by spin coating for solar demonstration of thermochemical water-splitting

摘要

A Ferrite/zirconia foam device in which reticulated ceramic foam was coated with zirconia-supported Fe_3O_4 or NiFe_2O_4 as a reactive material was prepared by a spin-coating method. The spin-coating method can shorten the preparation period and reduce the coating process as compared to the previous wash-coating method. The foam devices were examined for hydrogen productivity and cyclic reactivity in thermochemical two-step water-splitting. The reactivity of these foam devices were studied for the thermal reduction of ferrite on a laboratory scale using a sun simulator to simulate concentrated solar radiation, while the thermally reduced foam devices were reacted with steam in another quartz reactor under homogeneous heatingin an infrared furnace. The most reactive foam device, NiFe_2O_4/m-ZrO_2/ MPSZ, was tested for successive two-step water-splitting in a windowed single reactor using solar-simulated Xe-beam irradiation with a power input of 0.4-0.7 kW_(th). The production of hydrogen continued successfully in the 20 cycles that were demonstrated using the NiFe_2C_4/ m-ZrO_2/MPSZ foam device. The NiFe_2O4/m-ZrO_2/MPSZ foam device produced hydrogen at a rate of 1.1-4.6 cm3 per gram of device through 20 cycles and reached a maximum ferrite conversion of 60%.