Development of the high performance magnesium based hydrogen storage alloy

摘要

Series of MgNi type alloys with Ti, Al, Zr, Pd and Co additive elements were synthesized by mechanical alloying and their electrochemical hydrogen storage characteristics were investigated. Systematical alloy designing indicated that Mg_(0.80)Ti_(0.15)Al_(0.05)Zr_(0.05)Ni_(0.95) alloy has the best electrode performance. The atomic fractions in this alloy were believed to be optimum to get the reasonable amount of hydrogen storage with the improved cyclic stability. Titanium was estimated to enter into Mg(OH)_2 layer during the discharging process and make this barrier layer more penetrable by elemental hydrogen. Al and/or Al-oxides were predicted to dissolve selectively throughout the barrier hydroxide layer and thus reduce the stability of this layer. The main contribution of Zr was estimated to arise from its large atomic size that Zr atoms can create extra sites for the elemental hydrogen in the alloy structure. As the alloy charge transfer resistances decreased, the alloy retention rates increased. Improvement in the alloy capacity retaining rate was also closely related with the hydrogen diffusion coefficients in the alloy.