Impact of the reaction conditions on the photocatalytic reduction of water on mesoporous polymeric carbon nitride under sunlight irradiation

摘要

Sacrificial hydrogen evolution was studied with sol-gel prepared carbon nitride photo-catalysts loaded in-situ with platinum in a photocatalytic setup with defined geometry and a solar simulator as light source. Reaction conditions (e.g. photocatalyst concentration, triethanolamine concentration, amount of Pt precursor, water quality, etc.), and catalyst properties (e.g. BET surface area) were varied to optimize the catalysts for hydrogen evolution. We found that most of the parameters strongly influence the in-situ co-catalyst loading. The optimum platinum loading is between 0.03 and 0.09 wt%, which is less than 5% of the initial amount of platinum. A long term stability test was conducted showing a stable hydrogen evolution rate for more than 10 days indicating a stable catalyst under applied reaction conditions. We found that a change in the BET surface area affects the photocatalytic activity rather than the experimental conditions.