Improving temperature uniformity and performance of CO preferential oxidation for hydrogen-rich reformate with a heat pipe

摘要

Preferential oxidation (PROX) is an effective, but highly temperature-sensitive, method of CO removal for hydrogen-rich reformates. In a packed-bed catalytic reactor, oxidation is strongest at the inlet side and the local catalyst pellets become over-heated with poor heat conduction. As a result, the enhanced parasitic H_2 oxidation consumes oxygen and suppresses CO conversion. This study applies a heat pipe to improve the temperature uniformity in a tubular one-stage packed-bed reactor by transporting heat downstream and thereby improve CO removal. In the experiments, the fuel mixture containing 2% of CO, 75% of H_2, and 23% of CO_2, further mixed with air at O_2/CO = 0.75, 1.0 or 1.25, is supplied with stepwise increase of feeding rate under a fixed environmental temperature of 99 ± 1 ℃. The proposed simple method is found to significantly improve temperature uniformity and CO removal for the present test conditions with O_2/CO = 1.0 and 1.25.