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Evaluation of Ni-Cr-P coatings electrodeposited on low carbon steel bipolar plates for polymer electrolyte membrane fuel cell

机译:电沉积在低碳钢双极板上用于聚合物电解质膜燃料电池的Ni-Cr-P涂层的评估

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摘要

Polymer electrolyte membrane fuel cell (PEMFC) stacks suffer from the high cost and low volumetric energy of non-porous graphite bipolar plates. To resolve this problem, a bilayer coating consisting of Ni and Ni–Cr–P is deposited on AISI 1020 low-carbon steel using pulse electrodeposition. Ni/Ni–Cr–P-coated AISI 1020 is evaluated as a bipolar plate material for PEMFCs. Ni/Ni–Cr–P-coated substrates exhibit better corrosion resistance in both cathodic (air-purging) and anodic (H2-purging) environment than the bare AISI 1020 substrate and lower interfacial contact resistance (ICR) than bare AISI 1020 and stainless steel. Further, it is expected to show better water management as the Ni/Ni–Cr–P coating is more hydrophobic than the bare substrate. Preliminary studies show that Ni/Ni–Cr–P-coated AISI 1020 plate can be a suitable candidate for replacing graphite as the bipolar plate of PEMFCs.
机译:聚合物电解质膜燃料电池(PEMFC)堆遭受无孔石墨双极板的高成本和低体积能的困扰。为了解决这个问题,使用脉冲电沉积法在AISI 1020低碳钢上沉积了由Ni和Ni–Cr–P组成的双层涂层。 Ni / Ni–Cr–P涂层AISI 1020被评估为PEMFC的双极板材料。 Ni / Ni–Cr–P涂层的基材在阴极(空气吹扫)和阳极(H2吹扫)环境下均比AISI 1020裸露的基材更好,并且界面接触电阻(ICR)低于AISI 1020和不锈钢钢。此外,由于Ni / Ni–Cr–P涂层比裸露的基材更具疏水性,因此有望显示出更好的水管理性能。初步研究表明,Ni / Ni-Cr-P涂层的AISI 1020板可以替代PEMFCs的双极板,替代石墨。

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