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Study of Temperature Effect on the Corrosion Inhibition of C38 Carbon Steel Using Amino-tris(Methylenephosphonic) Acid in Hydrochloric Acid Solution

机译:氨基三(甲基膦)酸在盐酸溶液中温度对C38碳钢缓蚀作用的研究

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摘要

Tafel polarization method was used to assess the corrosion inhibitive and adsorption behaviours of amino-tris(methylenephosphonic) acid (ATMP) for C38 carbon steel in 1 M HC1 solution in the temperature range from 30 to 60℃. It was shown that the corrosion inhibition efficiency was found to increase with increase in ATMP concentration but decreased with temperature, which is suggestive of physical adsorption mechanism. The adsorption of the ATMP onto the C38 steel surface was found to follow Langmuir adsorption isotherm model. The corrosion inhibition mechanism was further corroborated by the values of kinetic and thermodynamic parameters obtained from the experimental data.
机译:用Tafel极化法评价了氨基三(亚甲基膦酸)酸(ATMP)对C38碳钢在1 M HC1溶液中在30至60℃温度范围内的缓蚀和吸附行为。结果表明,随着ATMP浓度的增加,缓蚀效率提高,而随着温度的升高,缓蚀效率降低,提示其物理吸附机理。发现ATMP在C38钢表面上的吸附遵循Langmuir吸附等温线模型。从实验数据获得的动力学和热力学参数值进一步证实了缓蚀机理。

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  • 来源
    《International journal of corrosion》 |2011年第2期|1-8|共8页
  • 作者单位

    Laboratoire de Spectroscopie Infrarouge, Faculte des Sciences, University Med V Agdal, avenue Ibn Battouta, BP1014, Rabat 10000, Morocco,Unite Materiaux et Transformations (UMET), Ingenierie des Systemes Polymeres CNRS UMR 8207, ENSCL, BP 90108, 59652 Villeneuve d'Ascq Cedex, France;

    Laboratoire de Chimie de Coordination et d'Analytique, Faculte des Sciences, Universite Chouaib Doukkali, BP 20, El Jadida 24000, Morocco;

    Unite Materiaux et Transformations (UMET), Ingenierie des Systemes Polymeres CNRS UMR 8207, ENSCL, BP 90108, 59652 Villeneuve d'Ascq Cedex, France;

    Unite Materiaux et Transformations (UMET), Ingenierie des Systemes Polymeres CNRS UMR 8207, ENSCL, BP 90108, 59652 Villeneuve d'Ascq Cedex, France;

    Laboratoire de Spectroscopie Infrarouge, Faculte des Sciences, University Med V Agdal, avenue Ibn Battouta, BP1014, Rabat 10000, Morocco;

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