Novel Iron(II) Microporous Spin-Crossover Coordination Polymers with Enhanced Pore Size

摘要

In this Communication, we report thensynthesis and characterization of novel Hofmann-likenspin-crossover porous coordination polymers of compositionn{Fe(L)[M(CN)4]}·G [L = 1,4-bis(4-pyridylethynyl)-nbenzene and MII = Ni, Pd, and Pt]. The spin-crossovernproperties of the framework are closely related to thennumber and nature of the guest molecules included in thenpores.