Ferroelectric nylon materials and their feasibility for ultrasound transducers

摘要

Measurements of the high frequency electrical and acoustic properties of oriented ferroelectric nylon-7 and nylon-11 are reported for the frequency range of 10 to 50 MHz and temperature range of 20 to 160/spl deg/C. The dielectric properties of nylon films were measured over a broadband frequency range including the fundamental halfwave resonance frequency for each sample, and a curve-fitting resonance technique was used to determine the properties of interest for ultrasound transducer design. Despite the high remanent polarization measured in the nylon films (1.25 mC/cm/sup 2/), the measured electromechanical coupling constant (k/sub t/=0.11), and mechanical quality factor (Q/sub m/=8) were lower than typically seen for PVDF and P(VDF-TrFE) copolymer. Poor thickness uniformity of the nylon film samples is suspected of dampening the features of the dielectric spectra near resonance, resulting in lower measured values for k/sub t/ and Q/sub m/. Comparisons of both simulated and actual measured pulse-echo performance showed the nylon materials to be competitive with PVDF for ultrasonic transducer performance. Actual pulse-echo tests with nylon-7 yielded a -6 dB fractional bandwidth of 144%. Since the ferroelectric nylons are known to be hydrophilic, tests were conducted to quantitatively determine the effects of water absorption on the ultrasonic performance of nylon-7 transducers. The results showed the water exposure slightly reduces the pulse-echo amplitude response and resonant frequency of a nylon-7 transducer. The water absorption effects were shown to be fully reversible upon drying the nylon film.