Preparation of porous carbons from petroleum coke by different activation methods

摘要

Dalian University of Technology, 158 Zhongshan Road, P.O. Box 49, Dalian 116012,China Porous carbons were prepared from Shengli petroleum coke (SPC) and Minxi petroleum coke (MPC) by different activation methods with H_2O, KOH and/or KOH + H_2O as active agents. The porous carbons were characterized by nitrogen adsorption at 77 K. It has been found that activation method and component of petroleum coke, of which different kinds of transitional metals on petroleum coke are crucial for preparing high quality porous carbons. Under the identical experimental conditions, the co-activation with KOH and H_2O as active agents in the same activation process, which has been rarely reported in literature, is the easiest method for the preparation of porous carbons with high surface area. The sequence of active agents in terms of difficulty in the preparation of porous carbons with high surface area is as follows: KOH + H_2O > KOH > H_2O. A drawback of KOH + H_2O activation in the preparation of porous carbon in this work is found to be its low carbon yield in comparison to KOH activation. Compared with the SPC coke, the MPC coke with higher contents of transitional metal and carbon and lower content of nitrogen is more suitable for making high surface area porous carbons, which is believed to be mainly due to the difference in the contents of transitional metals. Porous carbon with surface area around 2500-3000 m~2/g and carbon yield about 25-30% has been obtained from MPC coke by KOH + H_2O activation with less KOH and shorter activation time in comparison to the traditional methods.