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Experimental study on performance evaluation of PEM fuel cell by coating bipolar plate with materials having different contact angle

机译:用不同接触角的材料涂覆双极板来评估PEM燃料电池性能的实验研究

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Bipolar plates that have generally been made of graphite or composite materials are a fuel cell component that must be mechanically durable, easy to process, corrosion resistant, electrically and thermal conductive in contact with a gas diffusion layer, which is a porous material. In this study, instead of developing new materials with above features, water management has been improved by coating the bipolar plates and performance review has been carried out experimentally. The flow channels of the bipolar plates were coated with PTFE and SiO2. Physical vapor deposition (PVD) was used as the coating method. After the coating process, 120.2 degrees contact angle with PTFE and 35 degrees contact angle with SiO2 was approximately obtained in the flow channels. Single cell and 3-cell stack tests were performed with bipolar plates coated with these materials and uncoated polymer composite bipolar plates for given variable O-2 and H-2 flow rate and cell temperature at constant humidification conditions. 3-cell stack were tested after assembly. In PEM fuel cell stack tests, the highest current and power density values were also obtained in the hydrophobic PTFE coated plates. But in hydrophilic fuel cell stack, no voltage and current values could be measured due to the sudden decreases due to excessive flooding of the flow channels. A decrease in power density by 12.53% was observed when the single cell having hydrophobic flow channels with coated PTFE compared to 3-cell stack at the same operating conditions.
机译:通常由石墨或复合材料制成的双极板是燃料电池部件,该燃料电池部件必须机械耐用,易于加工,耐腐蚀,与作为多孔材料的气体扩散层接触具有导电性和导热性。在这项研究中,不是开发具有上述特征的新材料,而是通过涂覆双极板来改善水管理,并通过实验进行了性能评估。双极板的流道涂有PTFE和SiO2。使用物理气相沉积(PVD)作为涂覆方法。涂覆过程之后,在流道中大约获得了与PTFE的120.2度接触角和与SiO2的35度接触角。对于给定的可变O-2和H-2流量以及恒定的加湿条件下的电池温度,用涂覆有这些材料的双极板和未涂覆的聚合物复合双极板进行单电池和3电池堆测试。组装后测试3电池堆。在PEM燃料电池堆测试中,在疏水性PTFE涂层板中也获得了最高的电流和功率密度值。但是在亲水性燃料电池堆中,由于流动通道的过多溢流导致突然降低,因此无法测量电压和电流值。与在相同工作条件下的3单元电池组相比,当疏水性通道带有涂层PTFE的单电池与3单元电池组相比时,功率密度降低了12.53%。

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