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Decontamination efficiency of a new post-consumer poly(ethylene terephthalate) (PET) recycling concept

机译:消费后新的聚对苯二甲酸乙二醇酯(PET)回收概念的去污效率

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The aim of the study was to investigate and evaluate the cleaning efficiency of a new recycling concept for post-consumer poly(ethylene terephthalate) (PET). The so-called Flake To Resin (FTR~R) recycling process produces PET pellets or preforms from conventionally recycled PET flakes for the application in new PET packaging in direct food contact. The investigated process can be considered as 'super-clean' recycling process and was developed to introduce conventional recycled post-consumer (PCR) PET flakes up to an amount of 50% into the pellet and preform production. Within the study the cleaning efficiency of the investigated FTR process was determined by a challenge test. The experimental results obtained from three challenge tests with different input concentrations of the surrogates and different amounts of post-consumer PET flakes show that all applied surrogates are very efficiently removed by the investigated recycling process. The cleaning efficiencies for all surrogates are above 99.9%. In the final product of the process no surrogates could be determined above the detection limits (0.5 mg kg~(-1)) even if the initial concentrations were in the percentage range. From a migrational point the final product, which are either PET pellets or preforms, was similar to virgin PET. Only the PET typical substances acetaldehyde and ethylene glycol had slightly higher concentrations than found in a conventional PET virgin sample used as reference. The generally accepted migration limit of 10 μg kg~(-1) for the surrogates in the final products of the challenge tests is established for all kinds of foodstuffs.
机译:该研究的目的是调查和评估消费后聚对苯二甲酸乙二醇酯(PET)的新回收概念的清洁效率。所谓的薄片到树脂(FTR〜R)回收过程是使用传统回收的PET薄片生产PET颗粒或预成型坯,用于直接与食品接触的新PET包装中。被研究的过程可以被认为是“超清洁”的回收过程,其开发目的是将常规的回收消费后(PCR)PET薄片引入颗粒和预成型件生产中的比例高达50%。在研究中,通过挑战测试确定了所研究的FTR工艺的清洁效率。通过三种挑战测试获得的实验结果表明,不同替代物的输入浓度和消费后的PET薄片的量不同,所研究的回收过程可非常有效地去除所有应用的替代物。所有替代产品的清洁效率均高于99.9%。在该方法的最终产品中,即使初始浓度在百分比范围内,也无法检测出高于检测限(0.5 mg kg〜(-1))的替代物。从迁移的角度来看,最终产品(PET颗粒或预成型坯)与原始PET相似。仅PET典型物质乙醛和乙二醇的浓度略高于用作参考的常规PET原始样品中的浓度。建立了针对各种食品的挑战试验最终产品中替代物的公认的10μgkg〜(-1)的迁移极限。

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