Modification of pineapple peel fibre with succinic anhydride for Cu~(2+), Cd~(2+) and Pb~(2+) removal from aqueous solutions

摘要

Research on chemical modification of pineapple peel fibre with succinic anhydride was carried out to create a novel adsorbent for Cu~(2+), Cd~(2+) and Pb~(2+) removal from aqueous solution. After pretreatment with iso-propyl alcohol and NaOH, pineapple peel fibre was modified via reaction with succinic anhydride for introduction of carboxylic functional groups. The modified pineapple peel fibre was characterized with Fourier transform infrared (FTIR) spectroscopy and evaluated for its adsorptive ability for Cu~(2+), Cd~(2+) and Pb~(2+) from synthetic metal solutions. The FTIR analysis proved the introduction of carboxylic functional groups in the backbone of the modified pineapple peel fibre. The modified pineapple peel fibre showed higher adsorptive capacity for Cu~(2+), Cd~(2+) and Pb~(2+) compared with raw pineapple peel and pineapple peel fibre pretreated with iso-propyl alcohol. The adsorption of Cu~(2+), Cd~(2+) and Pb~(2+) on the modified pineapple peel fibre depended on solution pH value, adsorption time and initial metal concentration. The maximum adsorption capacities of the modified fibre were observed at pH 5.4 for Cu~(2+) (27.68 + 0.83 mg g~(-1) or 0.44 mmol g~(-1)), at pH 7.5 for Cd~(2+) (34.18 + 1.02 mg g~(-1) or 0.30 mmol g~(-1)) and at pH 5.6 for Pb~(2+) (70.29 ± 2.11 mg g~(-1) or 0.34 mmol g~(-1)) respectively. The adsorption followed the pseudo-second-order kinetics model and the experimental data coincided well with the Langmuir model.