Efficient removal of Pb(Ⅱ) through recycled biochar-mineral composite from the coagulation sludge of swine wastewater

摘要

Zeolite-Mg/Fe chloride dual enhanced coagulation is a cost-effective method for advanced treatment of swine wastewater, but the sludge generated after the enhanced coagulation remains to be a problem. In this study, the precipitate from a swine wastewater coagulation unit was regenerated by pyrolysis treatment in an O_2-limited environment to develop a high efficient adsorbent (biochar-mineral composite, BMC) for the removal of Pb(Ⅱ) from wastewater. SEM images indicate that complex Mg/Fe oxides and sludge biochar gathered around zeolite particles. Effects of different influencing factors such as Pb(Ⅱ) initial concentration, pH, adsorption time and ion concentration on the adsorption performance were investigated. The results show that the Langmuir isotherm model can better express the adsorption of Pb(Ⅱ) on BMC than Freundlich model and Temkin model. BMC py-rolyzed at 500 °C showed the maximum adsorption capacity of 450.58 mg/g under experimental condition of 25 °C, 100 mg/L Pb(Ⅱ) initial concentration and the initial pH of 5.6. The adsorption mechanisms on BMC mainly include ion exchange, electrostatic interaction. Therefore, it is a cost-effective and environmental-friendly strategy to obtain biochar-mineral composite from recycled sludge, which can efficiently remove Pb(Ⅱ) from wastewater.