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An overview of policies for managing polybrominated diphenyl ethers (PBDEs) in the Great Lakes basin

机译:大湖流域管理多溴联苯醚(PBDEs)的政策概述

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摘要

The Great Lakes are an important environmental and economic resource for Canada and the United States. The ecological integrity of the Great Lakes, however, is becoming increasingly threatened by a number of persistent, bio-accumulative and harmful chemicals that enter the Great Lakes ecosystem through fluvial and atmospheric deposition. Polybrominated diphenyl ethers (PBDEs), a class of brominated flame retardant, are among such chemicals, whose concentration in the Great Lakes has greatly increased in recent years. Despite growing concern over the possible health and environmental effects of these compounds, only four of the eight Great Lakes states have enacted regulations to ban/restrict the use of PBDE while the two Canadian Great Lakes provinces are yet to endorse any regulation. Of the three main commercial PBDE mixtures (pentaBDE, octaBDE and decaBDE), penta- and octaBDE are no longer manufactured or imported into the United States and Canada. DecaBDE, however, still finds use in a variety of products. In the present paper, the authors review the current regulations and policies for managing PBDEs in the Great Lakes jurisdictions and briefly review commercially available non-bromine chemical alternatives to PBDE. As these alternatives are comparatively more expensive than PBDE, future adoption of more eco-friendly flame retardants by the polymer industry will likely depend on stricter legislation regulating the use of PBDE and/ or an increased public demand for PBDE-free products.
机译:五大湖是加拿大和美国的重要环境和经济资源。然而,通过河流和大气沉积进入大湖生态系统的多种持久性,生物蓄积性和有害化学物质正日益威胁着大湖的生态完整性。多溴二苯醚(PBDEs)是一类溴化阻燃剂,属于此类化学品,近年来在大湖区的浓度大大增加。尽管人们日益担心这些化合物可能对健康和环境产生的影响,但八个大湖州中只有四个州颁布了禁止/限制使用多溴二苯醚的法规,而加拿大的两个大湖区省尚未批准任何法规。在三种主要的商用多溴二苯醚混合物(五溴二苯醚,八溴二苯醚和十溴二苯醚)中,五溴和八溴二苯醚不再生产或进口到美国和加拿大。然而,十溴二苯醚仍可用于多种产品中。在本文中,作者回顾了大湖地区辖区管理PBDEs的现行法规和政策,并简要回顾了PBDE的市售非溴化学替代品。由于这些替代品比PBDE相对昂贵,因此聚合物行业未来采用更环保的阻燃剂将可能取决于更严格的法规来规范PBDE的使用和/或公众对不含PBDE的产品的需求增加。

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