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Removing CO_2 and H_2S from the Gas Produced during Underground Coal Gasification (UCG)

机译:从地下煤气化(UCG)产生的气体中去除CO_2和H_2S

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摘要

The new method of simultaneous disposal of CO_2 and H_2S in coal gas generated during underground coal gasification (UCG) using industrial waste alkali liquor is put forward and studied for the first time. The rationale of absorption of CO_2 and H_2S by the alkali liquor is analyzed, and the mass transfer model for the above process is established. The impact of the existence of H_2S on absorbing CO_2 by the alkali liquor is studied on the basis of the model experiment. Research shows that as the velocity of coal gas increases, the selection coefficient of H_2S improves, the temperature rises, the selection coefficient of H_2S deceases, but the removal rate of CO_2 increases. By means of study, it can be found that the removal rate of CO_2 can reach more than 60% under the conditions of the suitable concentration of the alkali liquor and the ratio of liquid to gas, the heat value of underground coal gas can heighten by 12.3%, 17.7%, and over 20%, respectively, when the removal rate of CO_2 is 58%, 80%, and greater than 90%.
机译:提出并研究了利用工业废碱液同时处理地下煤气化过程中产生的煤气中CO_2和H_2S的新方法。分析了碱液吸收CO_2和H_2S的基本原理,建立了上述过程的传质模型。在模型实验的基础上,研究了H_2S的存在对碱液吸收CO_2的影响。研究表明,随着煤气速度的增加,H_2S的选择系数提高,温度升高,H_2S的选择系数降低,但CO_2的去除率增加。通过研究发现,在适当的碱液浓度和液气比的条件下,CO_2的去除率可达到60%以上,可提高地下煤气的热值。当CO_2的去除率为58%,80%和大于90%时,分别为12.3%,17.7%和20%以上。

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