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Cetane Number Assessment in Diesel Fuel by ~1H or Hydrogen Nuclear Magnetic Resonance-Based Multivariate Calibration

机译:通过〜1H或基于氢核磁共振的多元标定评估柴油中十六烷值

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摘要

The cetane number (CN) is one of the most important parameters regarding diesel fuel oil quality, mainly ignition properties. Traditionally, the CN determination is performed by a quite laborious and high-cost method on an explosion engine. On the other hand, nuclear magnetic resonance (NMR) spectroscopy is increasing as a versatile tool for quality control in several areas, such as petroleum and fuels, which permits the fast and direct investigation on samples. In this work, two NMR-based methods for CN determination based on multivariate calibration were developed with advantages of time saving, without the need of any sample treatment.
机译:十六烷值(CN)是关于柴油质量,最主要是着火性能的最重要参数之一。传统上,CN确定是通过相当费力且成本高的方法对爆炸引擎执行的。另一方面,核磁共振(NMR)光谱作为一种用于控制多个领域(例如石油和燃料)质量的通用工具,正在不断增加,这允许对样品进行快速直接的研究。在这项工作中,开发了两种基于NMR的基于NMR的CN确定方法,具有节省时间的优点,无需任何样品处理。

著录项

  • 来源
    《Energy & fuels》 |2014年第julaaauga期|4958-4962|共5页
  • 作者单位

    NMR Center, and Department of Chemistry, Federal University of Parana (UFPR), 81530-900 Curitiba, Parana, Brazil;

    NMR Center, and Department of Chemistry, Federal University of Parana (UFPR), 81530-900 Curitiba, Parana, Brazil;

    Development of Advanced Techniques for Residues Treatment Group, Department of Chemistry, Federal University of Parana (UFPR), 81530-900 Curitiba, Parana, Brazil;

    Getulio Vargas's President Refinery (REPAR), Petrobras, 83707-440 Araucaria, Parana, Brazil;

    NMR Center, and Department of Chemistry, Federal University of Parana (UFPR), 81530-900 Curitiba, Parana, Brazil;

    NMR Center, and Department of Chemistry, Federal University of Parana (UFPR), 81530-900 Curitiba, Parana, Brazil;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

  • 入库时间 2022-08-18 00:40:32

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