Assessing and improving cloud-height-based parameterisations of global lightning flash rate, and their impact on lightning-produced NO x and tropospheric composition in a chemistry–climate model

摘要

Although lightning-generated oxides of nitrogen (LNO x ) account for only approximately 10?% of the global NO x source, they have a disproportionately large impact on tropospheric photochemistry due to the conducive conditions in the tropical upper troposphere where lightning is mostly discharged. In most global composition models, lightning flash rates used to calculate LNO x are expressed in terms of convective cloud-top height via the Price and Rind (1992) (PR92) parameterisations for land and ocean, where the oceanic parameterisation is known to greatly underestimate flash rates. We conduct a critical assessment of flash-rate parameterisations that are based on cloud-top height and validate them within the Australian Community Climate and Earth System Simulator – United Kingdom Chemistry and Aerosol (ACCESS-UKCA) global chemistry–climate model using the Lightning Imaging Sensor and Optical Transient Detector (LIS/OTD) satellite data. While the PR92 parameterisation for land yields satisfactory predictions, the oceanic parameterisation, as expected, underestimates the observed flash-rate density severely, yielding a global average over the ocean of 0.33?flashes?s ?1 compared to the observed 9.16?flashes?s ?1 and leading to LNO x being underestimated proportionally. We formulate new flash-rate parameterisations following Boccippio's (2002) scaling relationships between thunderstorm electrical generator power and storm geometry coupled with available data. The new parameterisation for land performs very similarly to the corresponding PR92 one, as would be expected, whereas the new oceanic parameterisation simulates the flash-rate observations much more accurately, giving a global average over the ocean of 8.84?flashes?s ?1 . The use of the improved flash-rate parameterisations in ACCESS-UKCA changes the modelled tropospheric composition – global LNO x increases from 4.8 to 6.6?Tg?N?yr ?1 ; the ozone (O 3 ) burden increases by 8.5?%; there is an increase in the mid- to upper-tropospheric NO x by as much as 40?pptv, a 13?% increase in the global hydroxyl radical (OH), a decrease in the methane lifetime by 6.7?%, and a decrease in the lower-tropospheric carbon monoxide (CO) by 3?%–7?%. Compared to observations, the modelled tropospheric NO x and ozone in the Southern Hemisphere and over the ocean are improved by this new flash-rate parameterisation.