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Effect of Wood Fiber Surface Treatment on the Properties of Recycled HDPE/Maple Fiber Composites

机译:木纤维表面处理对再生HDPE /枫叶复合材料性能的影响

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This work reports on the production and characterization of recycled high density polyethylene (R-HDPE) composites reinforced with maple fibers. The composites were produced by a simple dry-blending technique followed by compression molding. Furthermore, a fiber surface treatment was performed using a coupling agent (maleated polyethylene, MAPE) in solution. FTIR, TGA/DTG, and density analyses were performed to confirm any changes in the functional groups on the fiber surface, which was confirmed by SEM-EDS. As expected, the composites based on treated fiber (TC) showed improved properties compared to composites based on untreated fiber (UC). In particular, MAPE was shown to substantially improve the polymer–fiber interface quality, thus leading to better mechanical properties in terms of tensile modulus (23%), flexural modulus (54%), tensile strength (26%), and flexural strength (46%) as compared to the neat matrix. The impact resistance also increased by up to 87% for TC as compared to UC. In addition, the maximum fiber content to produce good parts increased from 15 to 75 wt% when treated fiber was used. These composites can be seen as sustainable materials and possible alternatives for the development of low-cost building/construction/furniture applications.
机译:该工作报告了用枫叶纤维加固的再生高密度聚乙烯(R-HDPE)复合材料的生产和表征。复合材料是通过简单的干混技术生产,然后进行压缩成型。此外,使用溶液中的偶联剂(马来酸的聚乙烯,MAPE)进行纤维表面处理。进行FTIR,TGA / DTG和密度分析以确认通过SEM-EDS确认的纤维表面上的官能团的任何变化。如预期的那样,与基于未处理的纤维(UC)的复合材料相比,基于处理过的纤维(Tc)的复合材料显示出改善的性能。特别地,MAPE被证明基本上提高了聚合物 - 纤维界面质量,从而在拉伸模量(23%),弯曲模量(54%),拉伸强度(26%)和弯曲强度方面具有更好的机械性能(与整齐的基质相比,46%。与UC相比,抗冲击性也增加了87%的TC。此外,当使用处理的纤维时,产生良好部位的最大纤维含量从15%增加到75wt%。这些复合材料可以被视为可持续材料和开发低成本建筑/建筑/家具应用的可能替代方案。

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