Incorporation of Multiwalled Carbon Nanotubes and Graphene Nanoplatelets on the Morphology and Properties of Polyethylene Terephthalate Nanocomposites

摘要

In this work, the interaction effect between polyethylene terephthalate (PET) and multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) on the morphology and thermal properties of the nanocomposites have been investigated. PET nanocomposites with the incorporation of 0.1?wt% and 0.5?wt% of MWCNTs and GNPs were prepared by the melt compounding and injection moulding method. The presence of MWCNTs and GNPs in the PET matrix was confirmed by the X-ray diffraction (XRD) technique. MWCNTs and GNPs acted as a nucleating agent which enhanced the crystallization of PET/MWCNT/GNP nanocomposites at both weight percentages. The result obtained from thermogravimetric analysis (TGA) showed that the incorporation of MWCNTs and GNPs into pure PET improved the thermal stability of the nanocomposites. The nanofillers served as efficient heat sinks which prevent thermal degradation of PET. From the fractured cross-section morphology in field emission scanning electron microscope (FESEM), the nanofillers displayed good dispersion in the PET matrix. Better dispersion distribution found in 0.1?wt% PET/MWCNTs/GNPs nanocomposites compared to 0.5?wt% PET/MWCNTs/GNPs nanocomposites which favor less mechanical and physical failures like crack, delamination, and agglomeration.