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Preparation and Characterization of Chitosan/Polyvinyl Alcohol Blends-A Rheological Study

机译:壳聚糖/聚乙烯醇共混物的制备与表征 - 一种流变研究

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Blends of chitosan (CS) and polyvinyl alcohol (PVA) of different proportions (considering chitosan as the main component) were prepared. The rheological properties of the obtained blend solutions such as the shearing viscosity and the shear stress were investigated as a function of shear rate under various temperatures, shearing times and solution storage times using a digital viscometer. The CS/PVA solutions showed a Newtonian behavior at temperatures in the range of 40-55 °C regardless of the blend composition. This was accompanied by a general decrease in the viscosity with increasing PVA content in the blend. The heat-dependant viscosity changes of the blend solutions were found to follow Arrhenius equation. The shearing time was found to have no significant effect on the shearing viscosity of all blended solutions. However, the variation of solution storage period was found to have a mixed effect when time was extended to 3 weeks.
机译:制备不同比例的壳聚糖(Cs)和聚乙烯醇(PVA)的混合物(将壳聚糖视为主要成分)。通过使用数字粘度计在各种温度下的剪切速率,剪切时间和溶液储存时间下,研究了所得共混溶液的流变性能,例如剪切粘度和剪切应力。无论混合组合物如何,CS / PVA溶液在40-55°C的温度下显示出牛顿行为。这伴随着粘度的一般减少,随着混合物中的PVA含量增加。发现共混溶液的热依赖性粘度变化跟随Arhenius方程。发现剪切时间对所有混合溶液的剪切粘度没有显着影响。然而,发现溶液储存期的变异在时间延长至3周时,发现效果混合效果。

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