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N′-[(1E)-2,5-Di-meth-oxy-benzyl-idene]pyridine-2-carbohydrazide

机译:N' - [(1E)-2,5-二 - 甲氧苄基 - 硝基吡啶-2-碳水化物

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摘要

The mol-ecule of the title compound, C 15 H 15 N 3 O 3 , is twisted, with the dihedral angle between the pyridyl and benzene rings being 58.34?(6)°. In the crystal, amide-N—H?O(amide) and imine-C—H?O(amide) hydrogen bonds lead to zigzag (glide symmetry) chains extending along the c axis which are joined into layers parallel to the [100] direction by offset π – π stacking inter-actions between inversion-related benzene rings [centroid–centroid distance = 3.7468?(7)??] and by C—H? π (pyrid-yl) inter-actions. Pyridyl rings protrude from the surfaces of the layers and partially inter-calate with those of adjacent layers.
机译:标题化合物的摩尔饼,C 15 H 15 N 3 O 3扭曲,吡啶基和苯环之间的二偏角角为58.34°(6)°。在晶体中,酰胺-N-H?O(酰胺)和亚胺-C-H 2 O(酰胺)氢键导致沿C轴线延伸的锯齿形(滑动对称)链,该链条延伸到平行于[100的层中。 ]方向通过偏移π - π堆叠反转相关的苯环之间的互动动作[质心 - 质心距离= 3.7468?(7)??]和C-H? π(pyrid-yl)互动。吡啶基环从层的表面突出,并与相邻层的部分部分地间隔。

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