Use of Physicochemical Modification Methods for Producing Traditional and Nanomodified Polymeric Composites with Improved Operational Properties

摘要

Various aspects of the methods of physical and physicochemical modification of components of filled thermoplastic composite materials are analyzed, aimed at improving the surface properties of the fillers and the technological properties of the polymer matrix during their interaction. It is noted that the improvement of the interfacial interaction of the components of polymer reactoplastic composites, including adhesive strength, is a key factor for improving the reliability of the cured filled composite. As a promising area of research, a modification of the surface of the reinforcing fibrous filler and the technological characteristics of the liquid polymer binder, aimed at increasing their contact properties in the composite, was chosen. The effectiveness of the physical method of modifying the components of composites in the form of low-frequency ultrasonic processing is described. The peculiarities of cluster formation and physicochemical modification of epoxy polymers filled with dispersed fillers are analyzed. Attention is focused on the effectiveness of ultrasonic processing in the cavitation mode for deagglomeration and uniform distribution of nanoparticles in a liquid medium during the creation of nanocomposites. Experimentally confirmed is the improvement of the technological properties of liquid epoxy polymers, modified by ultrasound, used for the impregnation of oriented fibrous fillers, as well as the improvement of the physicomechanical properties of the sonicated epoxy matrices. Some issues of biological modifications of components of polymers for functional application are briefly reviewed.