Silver-Decorated Cobalt Ferrite Nanoparticles Anchored onto the Graphene Sheets as Electrode Materials for Electrochemical and Photocatalytic Applications

摘要

The present work describes the synthesis of Ag-CoFe_(2)O_(4)/rGO nanocomposite as a photocatalyst through the hydrothermal process by the attachment of silver and cobalt ferrite (CoFe_(2)O_(4)) nanoparticles on the surface of reduced graphene oxide. The effect of Ag and reduced graphene oxide (rGO) on the structure, optical, magnetic, photocatalytic, and electrochemical performance of the CoFe_(2)O_(4) is systematically explored through various analytical techniques. The analyses of the observed outcomes reveal that the graphene sheets are exfoliated and decorated with well-dispersed Ag and CoFe_(2)O_(4) nanoparticles. UV–vis spectra indicate a gradual shift in the absorption edge toward the higher wavelength with the addition of Ag ions, which signifies variation in the energy gap of the samples. Photoluminescence results divulge that graphene can decline the electron–hole recombination rate and improve the photocatalytic activity of the Ag-CoFe_(2)O_(4)/rGO nanocomposite. In this context, the Ag-CoFe_(2)O_(4)/rGO sample presents good catalytic activity as compared to the CoFe_(2)O_(4) and Ag-CoFe_(2)O_(4) photocatalysts for the degradation of methylene blue (MB) dye and suggests that the rGO plays a vital role in the Ag-CoFe_(2)O_(4)/rGO nanocomposite. The deterioration rate of the samples is found to be in the order of CoFe_(2)O_(4)(78.03%) < Ag-CoFe_(2)O_(4)(83.04%) < Ag-CoFe_(2)O_(4)/rGO(93.25%) in 100 min for MB dye, respectively, under visible-light irradiation. The room-temperature ferromagnetic behavior of the samples is confirmed by the M –H hysteresis loop measurements. Overall, the Ag-CoFe_(2)O_(4)/rGO nanocomposite promises to be a strong magnetic photocatalyst for contaminated wastewater treatment. The electrochemical performance of all of the samples was examined by the cyclic voltammetry (CV) that exhibits a superior rate performance and cycle stability of the Ag-CoFe_(2)O_(4)/rGO nanocomposite as compared to the other samples.