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Continuous Operation on Synthesis and Surface Modification of Rutile Nanoparticles in Designed Microfluidic Reactors

机译:设计微流体反应器中金红石纳米粒子合成和表面改性的连续操作

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Synthesis and surface modification of rutile nanoparticles (NPs) are two distinct processes. Conventionally, they should be conducted separately. In this work, synthesis and surface modification of rutile NPs are consecutively performed in a designed microfluidic system, thereby avoiding the pilot processes, giving a high controllability and low-energy consumption of the process, and the preparation process of the coated TiO_(2) is simplified effectively. Samples synthesized using different strategies are compared, and the results demonstrate that the sample prepared using the microfluidic method shows a smaller particle size (60 nm) and a narrower particle size distribution range than those synthesized using the other two methods. Rutile NPs are most commonly used in terms of suspensions, the stability of the suspensions consisting of the naked and coated samples are assessed in terms of turbidity, agglomeration size, and settlement rate. Response surface methodology is employed to quantify the effects of the factors on the stability of suspensions.
机译:金红石纳米颗粒(NPS)的合成和表面改性是两个不同的方法。传统上,它们应该单独进行。在这项工作中,在设计的微流体系统中连续进行金红石NP的合成和表面改性,从而避免了导频过程,为过程提供了高可控性和低能量消耗,以及涂层TiO_(2)的制备过程有效地简化。比较使用不同策略合成的样品,结果表明使用微流体方法制备的样品显示较小的粒径(60nm)和比使用其他两种方法合成的较窄的粒度分布范围。金红石NPS最常用于悬浮液方面,由裸露和涂覆的样品组成的悬浮液的稳定性在浊度,聚集尺寸和沉降率方面进行评估。应对响应面方法用于量化因素对悬浮液稳定性的影响。

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