Column Separation of Am(III) and Eu(III) by α-Zirconium Phosphate Ion Exchanger in Nitric Acid

摘要

The trivalent lanthanide-actinide separations are a major challenge in reprocessing ofnuclear fuels. To achieve this, commonly organic extractants and solvents are utilized in elaborateprocesses. Here we report a simple new method that can perform a supportive or alternative role.A nanocrystalline α-zirconium phosphate ion exchanger was utilized for Eu(III)/Am(III) columnseparation. Comprehensive preliminary studies were done using batch experiments to optimize thefinal separation conditions. The distribution coefficients for Eu were determined as a function ofpH (from 0 to 3) and salinity (Na, Sr). The distribution coefficients for Am were determined as afunction of pH, and Eu concentration, from 1:40 to 10,000:1 Eu:Am molar ratio. The exchanger alwayspreferred Eu over Am in our experimental conditions. Separation factors (Eu:Am) of up to 400 wereachieved in binary Eu-Am solution in pH 1. The breakthrough capacity was determined in dynamiccolumn conditions using Eu: 0.3 meq·g?1, which is approximately 4% of the theoretical maximumcapacity. Two types of hot column separation tests were conducted: (i) binary load (selective Amelution), and (ii) continuous equimolar binary feed. In both cases separation was achieved. In (i), themajority (82% of the recovered 93%) of Am could be purified from Eu with extremely high 99.999%molar purity, while alternatively even more (95% of the recovered 93%) at a lower purity of 99.7 mol%. In (ii), up to 330 L·kg?1 of the equimolar solution per mass of the exchanger could be treated withAm purity above 99.5 mol % in the total eluate. Alternatively, up to 630 L·kg?1 above 95 mol %, or upto 800 L·kg?1 above 90 mol % purities.