Separation of La(III), Eu(III), and Ho(III) with Sorbents Impregnated by Mixtures of Acidic Phosphoryl Podands and Amines in Nitric Acid Solutions

摘要

The possibility of separation of La(III), Eu(III), and Ho(III) as respective individual representatives of light, medium, and heavy rare earth elements was studied using sorbents impregnated by mixtures of acidic phosphoryl podands derived from diethylene glycol and octyl, dioctyl, and trioctyl amines from nitric acid solutions of various concentrations. The influence of the phosphoryl podands structure, their percentage content, and proportion in a sorbent and the nature of an acid on the efficiency of separation of La(III), Eu(III), Ho(III) was studied. It is shown that the greater is the concentration of HNO3, the smaller are the separation factors of REEs, and remarkably so. The most efficient separation is achieved with the concentration of HNO3 not over 0.04 mol/L. The optimal conditions of separation of La(III), Eu(III), and Ho(III) with the developed sorbent were found. Repeated use of the sorbent for the separation of La(III), Eu(III), and Ho(III) after its regeneration with 0.04 mol/L HNO3 was estimated. It was found that the efficiency of separation of REEs with the sorbents impregnated by a mixture of 1,5-bis(2-oxyethoxyphosphoryl-4-ethylphenoxy)-3-oxapentane and trioctylamine (TOA) exceeds markedly that made of a mixture of di-(2-ethylhexyl)phosphoric acid (DEHPA) and TOA.