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Exploring the complex free-energy landscape of the simplest glass by rheology

机译:通过流变学探索最简单玻璃的复杂自由能景观

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摘要

For amorphous solids, it has been intensely debated whether the traditional view on solids, in terms of the ground state and harmonic low energy excitations on top of it, such as phonons, is still valid. Recent theoretical developments of amorphous solids revealed the possibility of unexpectedly complex free-energy landscapes where the simple harmonic picture breaks down. Here we demonstrate that standard rheological techniques can be used as powerful tools to examine nontrivial consequences of such complex free-energy landscapes. By extensive numerical simulations on a hard sphere glass under quasistatic shear at finite temperatures, we show that above the so-called Gardner transition density, the elasticity breaks down, the stress relaxation exhibits slow, and ageing dynamics and the apparent shear modulus becomes protocol-dependent. Being designed to be reproducible in laboratories, our approach may trigger explorations of the complex free-energy landscapes of a large variety of amorphous materials.
机译:对于无定形固体,人们一直在争辩关于固体的传统观点,无论是基态还是声子等在其顶部的谐波低能激发,仍然有效。非晶态固体的最新理论发展表明,可能会出现意想不到的复杂自由能态势,其中简单的谐波图会崩溃。在这里,我们证明了标准的流变技术可以用作检查此类复杂自由能态势的重要成果的强大工具。通过在有限温度下在准静态剪切下对硬球玻璃进行的大量数值模拟,我们表明,在所谓的Gardner转变密度之上,弹性破裂,应力松弛表现出缓慢的趋势,并且时效动力学和表观剪切模量变为协议-依赖。由于设计为在实验室中可重现,我们的方法可能会触发对多种无定形材料的复杂自由能态的探索。

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