Development of method for determination of the kinetics constants of coal char gasification in pore diffusion regimes

摘要

In this paper, we developed a method for determining the kinetic constants of partially diffusion-controlled heterogeneous reactions in a porous sample of powder. Studies have been conducted on the experimental data of thermogravimetric analysis of carbon conversion in a stream of CO_(2), using a new method of processing kinetic curves, to obtain updated values of the kinetic constants under conditions where widely used models are inappropriate. Data obtained can be used for a reliable assessment of the characteristics of the gasification process.