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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide
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Crystal structure of benz­yl(meth­yl)phen­yl[(piperidin-1-ium-1-yl)meth­yl]silane bromide

机译:苄基(甲基)苯基[(哌啶-1-基-1-基)甲基]硅烷溴化物的晶体结构

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摘要

The title compound, C20H29NSi+·Br−, contains a chiral silicon atom but crystallizes as a racemate. The C—Si—C bond angles in the range of 103.64 (8)–111.59 (9)° are usual for tetra­hedral geometry. The piperidine ring shows a regular chair conformation with an equatorially positioned exocyclic N—C bond. In the crystal, there is a hydrogen bond between the ammonium cation and the bromide anion. The crystal packing shows the dominant inter­molecular inter­action to be the electrostatic attraction between the ammonium cation and the bromide anion.
机译:标题化合物C20H29NSi +·Br-含有手性硅原子,但结晶为外消旋体。对于四面体几何形状,C-Si-C键角通常在103.64(8)–111.59 C(9)°范围内。哌啶环显示规则的椅子构型,其带有赤道定位的环外NC键。在晶体中,铵阳离子和溴化物阴离子之间存在氢键。晶体堆积显示出主要的分子间相互作用是铵阳离子和溴化物阴离子之间的静电吸引。

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