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首页> 外文期刊>Acta Crystallographica Section E: Crystallographic Communications >Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one
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Crystal structure of 5-(4-benzyl­oxyphen­yl)-3-(4-meth­oxy­phen­yl)-6-methyl­cyclo­hex-2-en-1-one

机译:5-(4-苄氧基苯基)-3-(4-甲氧基苯基)-6-甲基环己-2--2-烯-1-酮的晶体结构

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摘要

The title compound, C27H26O3, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. In mol­ecule A, the plane of the central benzene ring forms dihedral angles of 75.78 (14) and 52.75 (16)° with that of the terminal benzene rings, and the dihedral angle between the planes of the terminal benzene rings is 51.49 (17)°. The corresponding values for mol­ecule B are 75.18 (14), 58.11 (16) and 47.91 (16)°, respectively. The cyclo­hexene ring adopts an envelope conformation in both mol­ecules, with the C atom to which is attached the central benzene ring as the flap. The crystal packing, is stabilized by C—H⋯π inter­actions.
机译:标题化合物C27H26O3在不对称单元中被两个独立的分子(A和B)结晶。在分子A中,中心苯环的平面与末端苯环的平面形成75.78(14)和52.75(16)°的二面角,末端苯环的平面之间的二面角为51.49(17) °。分子B的相应值分别为75.18(14),58.11(16)和47.91(16)°。环己烯环在两个分子中均具有包络构象,其中连接有中心苯环的C原子作为侧翼。晶体堆积通过CH-π相互作用而稳定。

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