Using the New Developed Equation to Reproduce the Enthalpies of Transfer of Urea from Water to Aqueous Ethanol, Propan-1-ol and Acetonitrile at 298 K

摘要

The enthalpies of transfer, ツH_tヨ, of urea from water to aqueous ethanol, EtOH, propan-1-ol, PrOH, and acetonitrile, MeCN, are reported and analysed in terms of the new solvation theory. The analyses show that the solvation of urea is random in the considered solvent mixtures. It is also found that urea interact more strongly with EtOH or PrOH than water.