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首页> 外文期刊>Journal of the Brazilian Chemical Society >Partial oxidation of methane to syngas on Rh/Al2O3 and Rh/Ce-ZrO2 catalysts
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Partial oxidation of methane to syngas on Rh/Al2O3 and Rh/Ce-ZrO2 catalysts

机译:在Rh / Al2O3和Rh / Ce-ZrO2催化剂上甲烷部分氧化为合成气

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摘要

The partial oxidation of methane with γ-Al2O3-, CeO2-, ZrO2- and Ce-ZrO2-supported rhodium catalysts was investigated. DRIFTS (diffuse reflectance infrared spectroscopy) measurements of adsorbed CO showed the formation of different rhodium species on different supports, which influenced the dispersion of the metal. The effects of the metal dispersion, oxygen storage capacity on the activity of these catalysts for the partial oxidation of methane are discussed.
机译:研究了用γ-Al2O3-,CeO2-,ZrO2-和Ce-ZrO2-负载的铑催化剂对甲烷的部分氧化。用DRIFTS(漫反射红外光谱法)对吸附的CO的测量表明,在不同的载体上形成了不同的铑,这影响了金属的分散。讨论了金属分散体,储氧量对这些催化剂对甲烷部分氧化的活性的影响。

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