Extraction method for the determination of atrazine, deethylatrazine, and deisopropylatrazine in agricultural soil using factorial design

摘要

An optimization procedure for the extraction of the herbicide atrazine (AT), and the main degradation products deethylatrazine (DEA) and deisopropylatrazine (DIA) from an oxisol soil sample was carried out, for a soil from the Southwest of Paraná State in Brazil, where AT is among the most largely employed herbicide. A comparison between shaking and ultrasound extraction was performed, to define a simple and fast extraction procedure, followed by the quantification using high performance liquid chromatography. It is important to inform that a factorial planning was employed, that was very important to define the best conditions of extraction by shaking. Appropriate recovery values were observed using soil samples from three different depths, as well as the relative standard deviation, suggesting the possibility to employ the proposed extraction method for quantification of AT, DEA and DIA in oxisol samples.