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Hot Corrosion Behavior of Superalloy in Different Corrosive Environments

机译:不同腐蚀环境下高温合金的热腐蚀行为

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Hot corrosion is a serious problem in aircraft, marine, industrial and land-base gas turbines. To obviate these problems, superalloy superfer 800H (Midhani grade) is one of the prominent materials for the high temperature applications. The present work investigates hot corrosion behaviour of superfer 800H exposed to two different molten salt environments Na2SO4 + 60% V2O5 and Na2SO4 + 5% V2O5 + 5% NaCl respectively, at 900oC under cyclic conditions. The weight change measurements made on during the experiments are used to determine the kinetics of hot corrosion. It is observed that the formation of scale rich in Cr2O3, NiO and spinel NiCr2O4 has contributed for the better hot corrosion resistance of superfer 800H. Inspection for 10, 20, 35 and 50 cycles reveals that after 10 cycles Crack has been initiated in the scale and it is clearly visible in the presence of NaCl salt. On subsequent cycles, crack propagates perpendicular to surface and as it encounters inclusions.
机译:在飞机,船舶,工业和陆基燃气轮机中,热腐蚀是一个严重的问题。为了消除这些问题,超级合金superfer 800H(Midhani级)是用于高温应用的重要材料之一。本工作研究了在循环条件下,在900oC下暴露于两种不同熔盐环境的Na2SO4 + 60%V2O5和Na2SO4 + 5%V2O5 + 5%NaCl的Superfer 800H的热腐蚀行为。实验期间进行的重量变化测量用于确定热腐蚀的动力学。可以看出,富含Cr2O3,NiO和尖晶石NiCr2O4的氧化皮的形成有助于Superfer 800H的更好的抗热腐蚀性能。检查10、20、35和50个循环后,发现在10个循环后,秤上开始出现裂纹,并且在存在NaCl盐的情况下清晰可见。在随后的循环中,裂纹垂直于表面并遇到夹杂物而扩展。

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