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Photoluminescence properties of gypsum

机译:石膏的光致发光特性

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The photoluminescence (PL) properties of four gypsums from three localities, namely, Inner Mongolia (China), Turkey, and Canada, are investigated at room temperature. Under 365-nm excitation, two types of gypsums from Inner Mongolia exhibit different luminescence colors, namely, yellow and cyan-white, and gypsums from Turkey and Canada exhibit yellow and bluish-white luminescence, respectively. The PL spectra of these gypsums consist of continuous sub-bands distributed in all visible wavelengths, and the excitation spectra of these gypsums consist of continuous sub-bands distributed in a wide range of wavelengths, i.e., 200-500 nm. The features of PL and excitation spectra suggest that the origin of luminescence from these gypsums may be luminescent organic substances included into crystals in the growth process rather than the impurity ions substituted for Ca~(2+).
机译:在室温下研究了来自三个地区(内蒙古(中国),土耳其和加拿大)的四种石膏的光致发光(PL)特性。在365 nm激发下,来自内蒙古的两种类型的石膏具有不同的发光颜色,分别为黄色和青白色,来自土耳其和加拿大的石膏具有分别的黄色和蓝白色发光。这些石膏的PL光谱由分布在所有可见波长的连续子带组成,这些石膏的激发光谱由分布在宽波长范围即200-500nm的连续子带组成。 PL和激发光谱的特征表明,这些石膏的发光起源可能是生长过程中晶体中包含的发光有机物质,而不是取代Ca〜(2+)的杂质离子。

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