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Synthesis, Characterization and Investigation Magnetic and Photovoltaic properties of FeVO4 Nanoparticles

机译:FeVO4纳米粒子的合成,表征和研究磁光性能

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This research reports a facile ultrasonic approach for the synthesis of iron vanadate (FeVO4) nanoparticles with the aid of ammonium metavanadate (NH4VO3) and Fe(NO3)3.9H2O as the starting reagents without adding external surfactant, capping agent or template in an aqueous solution. Furthermore, to examine the solar cell application of as-synthesized iron vanadate (FeVO4) nanoparticles, FTO/TiO2/FeVO4/Pt-FTO structure was created by deposited iron vanadate film on top of the TiO2 layer. The VSM magnetic measurement result shows that a maximum magnetization of 0.16 emu/g was obtained for FeVO4 nanoparticles after annealing at 550 °C for 150 min. The as- synthesized FeVO4 ferrite powders were characterized by X-ray diffraction, scanning Electron Microscopy, spectra energy dispersive analysis of X-ray, and vibrating sample magnetometer techniques. The X-ray diffraction study showed that pure anorthic phase of FeVO4 nanoparticles have been produced after calcinations at 550 °C for 150 min. Solar cell result indicates that an inexpensive solar cell could be developed by synthesis of FeVO4 nanoparticles through the ultrasonic approach.
机译:这项研究报告了一种简便的超声方法,以偏钒酸铵(NH4VO3)和Fe(NO3)3.9H2O作为起始试剂,无需在水溶液中添加外部表面活性剂,封端剂或模板即可合成钒酸铁(FeVO4)纳米粒子。此外,为了检查已合成的钒酸铁(FeVO4)纳米颗粒在太阳能电池中的应用,通过在TiO2层顶部沉积钒酸铁膜来创建FTO / TiO2 / FeVO4 / Pt-FTO结构。 VSM磁测量结果表明,在550°C退火150分钟后,FeVO4纳米颗粒的最大磁化强度为0.16 emu / g。通过X射线衍射,扫描电子显微镜,X射线的光谱能量色散分析和振动样品磁强计技术对合成的FeVO4铁氧体粉末进行了表征。 X射线衍射研究表明,在550°C煅烧150分钟后,已经生成了纯正的FeVO4纳米颗粒的正邻相。太阳能电池结果表明,可以通过超声方法合成FeVO4纳米颗粒来开发廉价的太阳能电池。

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