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Synthesis and characterization of epoxy/graphiteano-copper nanocomposite for the fabrication of bipolar plate for PEMFCs

机译:PEMFC双极板制造用环氧树脂/石墨/纳米铜纳米复合材料的合成与表征

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In this research, the synthesis of a suitable nanocomposite in terms of properties and economics for use in bipolar plates in proton-exchange membrane fuel cells (PEMFCs) has been carried out successfully. Nowadays, bipolar plates play a significant role in fuel cells which is absolutely important in renewable energy industry. So, epoxy/graphiteano-copper nanocomposite bipolar plates are prepared by bulk molding compound process. Graphite and nano-copper were added as primary and secondary fillers to the composite, respectively. Epoxy resin was selected since fabrication bulk molding can be done with ease and also because of its lower cost compared to other materials. Although graphite could increase conductive characteristics, it is not sufficient for bipolar plates. Therefore, we boost the conductive properties by increasing nano-copper. Due to the small size of nanoscale copper, it can be well dispersed in polymer and graphite matrix; nano-copper can release conductive properties perfectly throughout the composite. Different percentages of nano-copper, graphite and constant percentage of epoxy are used for this purpose. The electrical resistance, flexural strength, and density of composites were measured according to the applicable standards. The morphology of the prepared plate was studied by scanning electron microscopy (SEM) and X-ray diffraction (XRD) found that fillers disperse well in the matrix. Innovations in this work include improving properties and increasing the efficiency of the nanocomposite by adding metal nanoparticles (copper). Graphical Abstract
机译:在这项研究中,就性质和经济性而言,已经成功地进行了用于质子交换膜燃料电池(PEMFCs)中双极板的合适纳米复合材料的合成。如今,双极板在燃料电池中起着重要作用,这在可再生能源行业中绝对重要。因此,通过体模复合工艺制备了环氧/石墨/纳米铜纳米复合双极板。分别将石墨和纳米铜作为主要和辅助填料添加到复合材料中。选择环氧树脂是因为可以轻松进行批量成型,而且与其他材料相比成本较低。尽管石墨可以增加导电特性,但对于双极板而言,这还不够。因此,我们通过增加纳米铜来提高导电性能。由于纳米级铜的尺寸小,可以很好地分散在聚合物和石墨基体中。纳米铜可以完美地释放整个复合材料的导电性能。为此目的,使用不同百分比的纳米铜,石墨和恒定百分比的环氧树脂。根据适用的标准测量复合材料的电阻,抗弯强度和密度。通过扫描电子显微镜(SEM)和X射线衍射(XRD)研究了所制备板的形态,发现填料在基质中分散良好。这项工作中的创新包括通过添加金属纳米颗粒(铜)来改善性能并提高纳米复合材料的效率。图形概要

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