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Synthesis of hydrazide derivatives and study their application as corrosion inhibitors for carbon steel in acidic solution

机译:酰肼衍生物的合成及其在酸性溶液中对碳钢缓蚀剂的应用研究

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The inhibition efficiency of two novels ethoxylated (10 and 20 ethylene oxide units) streayl hydrazides against corrosion of carbon steel in 1 M HCl was investigated at different temperature ranges (25 – 55 ºC) by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization methods. The carbon steel surface morphology was investigated by scanning electron microscopy (SEM). The obtained results showed that the prepared inhibitors have good inhibition in 1 M HCl, and the inhibition efficiency increases with the inhibitor concentration at 25 ºC. At 600 ppm the corrosion rates increase with increasing the temperature. Polarization curves show that the inhibitors in hydrochloric acid act as mixed type inhibitors.
机译:通过电化学阻抗谱(EIS)和电势极化方法研究了两种新型乙氧基化(10个环氧乙烷单元和20个环氧乙烷单元)酰肼在1 M HCl中对碳钢的腐蚀的抑制作用。通过扫描电子显微镜(SEM)研究了碳钢的表面形态。获得的结果表明,所制备的抑制剂在1 M HCl中具有良好的抑制作用,并且在25ºC下,抑制效率随抑制剂浓度的增加而增加。在600 ppm时,腐蚀速率随温度升高而增加。极化曲线表明,盐酸中的抑制剂起混合型抑制剂的作用。

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